Switchable polarity in polymer solar cells using conjugated polyelectrolyte
Identifieur interne : 000028 ( Main/Repository ); précédent : 000027; suivant : 000029Switchable polarity in polymer solar cells using conjugated polyelectrolyte
Auteurs : RBID : Pascal:14-0085380Descripteurs français
- Pascal (Inist)
- Polyélectrolyte, Fluorène dérivé copolymère, Ammonium quaternaire copolymère, Copolymère alterné, Copolymère conjugué, Polymère fonctionnel, Couche ITO, Caractéristique courant tension, Inversion polarité, Travail sortie, Etude expérimentale, Couche contrôle polarité, Fluorène(9,9-bis[6-(triméthylammonio)hexyl]) copolymère.
English descriptors
- KwdEn :
Abstract
We report polarity-switchable polymer solar cells that use poly [(9,9-bis((6?-(N,N,N-trimethylammonium)hexyl)-2,7-fluorene)-alt-(9,9-bis(2-(2-(2-methoxy-ethoxy)ethoxy)ethyl)-9-fluorene))dibromide polyelectrolyte (WPF-6-oxy-F). By introducing WPF-6-oxy-F as a polarity-controlling layer, we selectively achieved polarity switching in the device operation. When we deposited the WPF-6-oxy-F film on the top of an active polymer layer, the device operated conventionally; holes moved to the transparent indium tin oxide (ITO) electrode. However, the device showed switched polarity when we changed the position of insertion of the WPF-6-oxy-F film to the top of the transparent ITO electrode. Then, the electrons moved to the transparent ITO electrode, leading to an inverted device.
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Pascal:14-0085380Le document en format XML
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<author><name>INSOO SHIN</name>
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<author><name>JIHOON LEE</name>
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<author><name sortKey="Oh, Seung Hwan" uniqKey="Oh S">Seung-Hwan Oh</name>
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<author><name sortKey="Hyun Kang, Phil" uniqKey="Hyun Kang P">Phil Hyun Kang</name>
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<author><name>YUN KYUNG JUNG</name>
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<author><name>SUNG HEUM PARK</name>
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<term>Copolymère conjugué</term>
<term>Polymère fonctionnel</term>
<term>Couche ITO</term>
<term>Caractéristique courant tension</term>
<term>Inversion polarité</term>
<term>Travail sortie</term>
<term>Etude expérimentale</term>
<term>Couche contrôle polarité</term>
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<front><div type="abstract" xml:lang="en">We report polarity-switchable polymer solar cells that use poly [(9,9-bis((6?-(N,N,N-trimethylammonium)hexyl)-2,7-fluorene)-alt-(9,9-bis(2-(2-(2-methoxy-ethoxy)ethoxy)ethyl)-9-fluorene))dibromide polyelectrolyte (WPF-6-oxy-F). By introducing WPF-6-oxy-F as a polarity-controlling layer, we selectively achieved polarity switching in the device operation. When we deposited the WPF-6-oxy-F film on the top of an active polymer layer, the device operated conventionally; holes moved to the transparent indium tin oxide (ITO) electrode. However, the device showed switched polarity when we changed the position of insertion of the WPF-6-oxy-F film to the top of the transparent ITO electrode. Then, the electrons moved to the transparent ITO electrode, leading to an inverted device.</div>
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<fC01 i1="01" l="ENG"><s0>We report polarity-switchable polymer solar cells that use poly [(9,9-bis((6?-(N,N,N-trimethylammonium)hexyl)-2,7-fluorene)-alt-(9,9-bis(2-(2-(2-methoxy-ethoxy)ethoxy)ethyl)-9-fluorene))dibromide polyelectrolyte (WPF-6-oxy-F). By introducing WPF-6-oxy-F as a polarity-controlling layer, we selectively achieved polarity switching in the device operation. When we deposited the WPF-6-oxy-F film on the top of an active polymer layer, the device operated conventionally; holes moved to the transparent indium tin oxide (ITO) electrode. However, the device showed switched polarity when we changed the position of insertion of the WPF-6-oxy-F film to the top of the transparent ITO electrode. Then, the electrons moved to the transparent ITO electrode, leading to an inverted device.</s0>
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